Hundreds of 5 letter words start with f. A few of those words include fable, facts, faint, faith, false, fancy, fatal, fault, favor, feast, felon, fever, fifth, fifty, fight, flack, flare, flash, forgo, forty, foyer, frail, frame, frank, fraud, fudge and fussy.
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Frown
A five (5) letter word that starts with Z and ends with F, there is none recorded. However, there is a word that starts with Z and ends with F. The word is a four (4) letter word: zarf, (noun) a metal holder for a coffee cup.
Feathers
Forest
Fireproof Foolproof