You can now catch mewtwo in cerulean cave, you can now catch entei/raikou/suicune depending on which starter Pokemon you chose, try the trainer tower on seven island, finish the pokedex because now you can trade with ruby and sapphire and emerald and Pokemon colosseum and Pokemon xd gale of darkness, train your Pokemon to level 100 and have fun!
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You can do this after you find the Ruby and the Sapphire for Celio in Pokemon FireRed. then you can trade with Ruby, Sapphire and Emerald.
beat the elite four with 60 owned Pokemon in your pokedex. celio will not tell you to get the ruby and Sapphire until u do
You can't catch a poliwag in Pokemon Sapphire. You have to trade from Pokemon Fire Red or Pokemon Leaf Green.
Blaziken or Toarkal.
you can not catch scyther in Pokemon ruby,emerald or sapphire . you have to trade them from Pokemon fire red or leaf green.