it is on the east side of cianwod city
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Union cave is the best place to obtain a Sandshrew in Pokemon SoulSilver. You must either trade one from a HeartGold game, or catch it in the Safari Zone (desert area).
The Odd Incense can be found in the Cerulean Cave along with Mewtwo himself.
You can catch a Misdreavus on Mt. Silver, The Cliff Cave, or the Safari Zone (has special requirements).
In Pokemon HeartGold and SoulSilver, you can go through Mt. Moon, but the cave is very small and can be explored through in five minutes with Pokemon repellent.
In Pokemon HeartGold and SoulSilver, you can find Articuno in the Seafoam Island cave. There is a small series of puzzles you have to solve, but eventually you'll get to Articuno which is at level 50