There's no Action Replay code for Zoroark in Pokemon HeartGold, because Zoroark does not exist in Pokemon HeartGold.
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There is not a known Darkrai Action Replay Code for Pokemon HeartGold and SoulSilver yet.
By Action Replay
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If you have action replay you can get any Pokemon you want. This feature works only in Pokemon Heartgold , Soulsilver and Platinum.