Prinplup
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Rotom is #152 in the Sinnoh Dex in Pokémon Platinum, you can find it by interacting with a TV in the Old Chateau in Eterna Forest during the in-game time of night which is between 8 PM and 4 AM.
Night starts at 8 PM in Platinum.
There are probly a total of 8 rare candies in Pokemon platinum
When its about 8:00 clock
route 229 (8%)