Antidisestablishmentarianism n. opposition to the withdrawal of state support or recognition from an established church, esp. the Anglican church in 19th-century England. Random House College Dictionary, 1975, pg 58 My personal favorite.
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What are some really long words that start with D?
Some longer than average words that start and end with the same letter are:straightforwardnessexperiencemilitarismmulticulturalismexterminatesuperfluousnesscatastrophicarachnophobiacharacteristicdecaffeinateddisenfranchisedexcommunicategrandstandinggroundbreakinglackadaisicalnationalizationnewspaperwomanproprietorshipspontaneousnesstranscendentalisttranscriptionist
The list would be too long to name all the ten letters words that start with G, but here are a few:GamekeeperGarbagemanGargantuanGarishnessGastronomeGastronomyGatekeeperGatheringsGemologistGeneralistGeneralizeGenerationGenerosityGenerouslyGentlenessGeocentricGeographerGeographicGeologicalGeriatricsGermicidalGhostwriteGhostwroteGhoulishlyGingersnapGingivitisGirlfriendGlasshouseGoalkeeperGovernableGovernmentGracefullyGraciouslyGraduationGramophoneGrandchildGranddaddyGrandstandGrapefruitGratefullyGratifyingGratuitiesGravestoneGreasinessGreedinessGreenhouseGregariousGrindstoneGroundsmanGroundworkGuardhouseGuesthouseGuillotineGunfighterGunslingerGymnasticsGynecology
By nice, do you mean long? Very long list, if you want official list, go to a dictionary. A long word that start with an r would be, Reindeer.
Compound words that start with fan:fanfarefanfoldfanglikefantailfantasyland