no, this is impossible darkrai came out after they were made. darkrai is impossible to obtain in any generation 1, 2, or 3 game. They were not programmed or even created yet. They were created after generation 4 games were released and can be obtained in Diamond, Pearl, and Platinum through a Nintendo event or a cheating device.
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you can't catch any hoenn Pokemon in firered or leafgreen you must trade hoenn Pokemon from ruby or sapphire or emerald to leafgreen or firered.
You can't catch Darkrai in Pokemon FireRed, it is a 4th generation Pokemon so therefore unavailable in any of the GBA Pokemon games.
You have to migrate the pokemon so any pokemon you have in your leafgreen can be in pal park but it disappears from your leafgreen
Not any hoenn Pokemon but firered and leafgreen can catch alot of kanto and johto Pokemon ruby and sapphire can and can't.
Any ghost type Pokemon can learn it.