Yes, yes there is: Keldo. A ledgendary water/fighting pokemon that you can only get in Black/White or Black/White 2
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Pokémon starting with the letter K:KabutoKabutopsKadabraKakunaKangaskhanKarrablastKecleonKeldeoKingdraKinglerKirliaKlangKlinkKlinklangKoffingKrabbyKricketotKricketuneKrookodileKrokorokKyogreKyurem
Some words starting with the letter K are:KiteKittenKryptonKitchenKalemiaKaratKnightKnitkindkookykilling
KeepingKnelledKeelingKillersKingpinKnowing
kayak
That would be the letter k.