It depends on what expansion packs you have... I'll just put professions out of the situation. In the base game of sims 3 a well paying job is the science career and the harder one is the military career because it leaves your sims stressed and exhausted. Also to earn more money make sure you check out the career tab and the skill tab next to the inventory tab. This will help you keep track of what you need to do to earn a promotion.
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i dot think you can have a job on sims 3 only on sims 3 ambitions:)
You can call your job and tell them that you quit.
You can't be a thief on the sims 2, but you can be one on the sims 3. To do that, you must get a job within the crimes or something...
No you can't start your own buisness you can only have a job on sims 3 you can't start your buisness.
You can't go in there or get a job from there.