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go into the mine after 8:00 pm
On Harvest Moon: DS and Harvest Moon: DS Cute, you get the third mine by reaching the bottom of the second mine, which is 255 floors deep.
it is in the second mine to get the second mine you have to complete the first mine
You can mine it in the 2nd mine at level 7-10
You can find Alexandrite on the first floor in the third mine.