level 85
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Raichu will not learn thunder.... but pikachu can learn it at level 45
Zapdos doesn't learn it by leveling up. You buy or find TM24(Thunderbolt) and then teach it to Zapdos.
Zapdos will learn Thunder on it's on sometime around level 60.
In Pokémon FireRed, the moves that Zapdos can learn through level-up and TMs are Peck, Thundershock, Thunderbolt, Tnunder, Thunder Wave, Agility, Detect, Charge, Drill Peck, Light Screen, Toxic, Roar, Sunny Day, Hidden Power, Hyper Beam, Protect, Rain Dance, Return, Frustration, Double Team, Shock Wave, Aerial Ace, Sandstorm, Facade, Secret Power, Rest and Steel Wing.
it dosent learn thunder but at level 15 it learns thunder shock