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I would recommend that you use on latios or latias w/e which they are because raquaza and kyogre are fairly easy to catch

You don't have to use your Master ball on anything. You can use it on Kyogre, but that's the easiest legendary to catch, so I don't recomend it. You could save it for later on, like for Rayquaza. That's MUCH harder to catch! It's at level 70 when you encounter it, but you could still catch it with a normal Pokeball (I did). And then, you could catch Latias with it, which would be the best in my opinion, because unless you have a Pokemon like Wobbufett, with the ability Shadow Tag that doesn't let the opponent escape from battle, then it would be pretty hard to catch. So I say catch Latias with your Master ball.

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Q: In Sapphire which Pokemon should use the master ball on?
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Related questions

Where to get a master ball in Pokemon sapphire?

In the Aqua Hideout.


How do you get a master ball in Pokemon Sapphire?

Right of Lilicove


How do you get a master ball in Pokemon sapphire after beating eilite four?

you can get a master ball by winning the lottery in lilycove


Where can you buy a master ball on Pokemon sapphire?

Master balls cannot be bought in any Pokemon game.


Should you use your master ball on Groudon in ruby or should you keep it?

keep it if your playing Pokemon Sapphire for the rare kyogre.


Do you have to weaken legendary Pokemon before capturing them with a master ball in Pokemon sapphire?

no the master ball works strait away without doing anything to the Pokemon


How can you easily catch Rayquaza in Pokemon sapphire?

throw a master ball


Once the master ball has been used can you get another in Pokemon sapphire?

there's only one but you can trad a Pokemon holding a master ball from another game


Where is a master ball in Pokemon sapphire?

Somewhere in the aqua hideout (you have to be in lilycove city)


When do you get the master ball on Pokemon sapphire?

team aqua hideout at lilycove city


How many master balls are in Pokemon sapphire?

there are 2 master ball s and a master ball is rare you can only use it for kyogre requaza groudon salmence fly gon and the rest of the strongest Pokemon a master ball always captures a Pokemon no Pokemon can break out its in possible


Where do you get legendary Pokémon in Pokémon Sapphire?

In order to catch your legendary Pokemon in Pokemon Sapphire, save your master ball For Rayquaza...you can catch KYogre/Groudon/both with either an Ultra Ball or Timer Ball.