you can get many with the Pokemon lottery, 3rd prize i think
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after you deliver the letter to steven in dewford cave you go back to rusboro to the company owner and he gives you the exp. share!!
give the exp share to a weak Pokemon when you use any Pokemon to fight exp goes to the fighting Pokemon and the 1 with the exp share.
after you deliver mr. stone's letter to slateport then you go back to Rustboro city and talk to mr. stone (top floor of Devon Co.) and he will give you an exp. share
after you have delivered the Devon Goods from Rustboro, go back and see the president!
No, only the Exp Share