Hippopotomonstrosesquippedaliophobia has only one word. It is one word, but it has 36 letters. P.S. It's the fear of long words.
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hippopotomonstrosesquippedaliophobia honorificabilitudinitatibus
Pneumonoultramicroscopicsilicovolcanoconiosis is 45 letters long... and The phobia is 36 letters long, so the lung disease is longer.
Twilight has 115,362 words in it.
407 words
34 words (not including single letter words)