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Pneumonoultramicroscopicsilicovolcanoconiosis is 45 letters long... and The phobia is 36 letters long, so the lung disease is longer.
The longest word starting with a "P" is pneumonoultramicroscopicsilicovolcanoconiosis, which has 45 letters and is in the Guinness Book of Records. It was, however, coined for the specific purpose of becoming the longest word, and is not a specifically recognized form of silicosis.
The first longest word in English is Lopado­temacho­selacho­galeo­kranio­leipsano­drim­hypo­trimmato­silphio­parao­melito­katakechy­menolopado­temacho­selacho­galeo­kranio­leipsano­drim­hypo­trimmato­silphio­parao­melito­katakechy­meno which contains 183 letters. The second longest word in English is Pneumonoultramicroscopicsilicovolcanoconiosis which contains 45 letters! It is pretty amazing! Look it up if you don't believe me! In fact if you look it up, you'll find a larger word containing 189,819! Amazing! floccinaucinihilipilification
Pneumonoultramicroscopicsilicovolcanoconiosis (also happens to be the longest word in the English language)