Shuckle can only make rare candies in gold/silver/crystal.
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On Pokemon emerald, just clone 99 Pokemon holding a rare candy.
Rare Candy isn't bought, you find it in Item Balls, or you are given one by the Trick Master.
equip rayquaza with rare candy
That cool little function is only available in gen II so unless you are playing games of that gen, the answer is no.
This will give you infinite rare candies:BFF956FA2F9EC50DIT REALY DOES WORKS!