First, Did you attach the NeverMeltIce to the Pokemon?
Steps to NeverMeltIce success:
Step#1) Select the Pokemon you would like to give NeverMeltIce to (let's use Beartic as our example).
Step#2) Click Give Item to Pokemon (Simple).
Step#3) Select the NeverMeltIce in your bag.
Now you have given Beartic NeverMeltIce.
Do you know how to cause the effect? Once Beartic is in battle against a fire Pokemon the item will know when to be used. Lets say your Beartic is battling a Simisear. Simisear used Flamethrower! But Simisear's Flamethrower won't work because the NeverMeltIce prevented it!
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You can get the Nevermeltice in the Shoal cave,which is on Route 125.But the tide has to be low though in the Shoal Cave.Then go to the part where there is frozen ice.And then go up the steps and you will get a Nevermeltice. When held by a Pokemon,the Nevermeltice raises the power of its Ice Type Moves.
Use repel and sprint around
Elite four, Celadon city and all other places where you can buy max repel are equally good
ou get that item in icefall cave its the item to the right of the big ice room.
In Pokemon Crater its an evolution stone used for example Piloswine->Mamoswine. I hope I helped you.