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Ash evolved Charmander into Charmeilan.
Ash got Charizard in episode 11
Charizard starts obeying Ash in the Orange League episode titled "Charizard Chills."
Ash and friends meet a girl named Liza, who protects the nearby Charicific Valley, a valley where wild Charizard live. Everyone goes there and Ash wants his Charizard to train with the others.So Ash decides that Charizard should stay in the Charicific Valley.
charizard burning ambition i think