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Play in story mode. The further you get, the more charactors you unlock.

You can also get them from winning a lot of brawls. It will say "challenger approching" and some new charactor will play a 1 on 1 brawl with you. If you win, that charactor will be added to you charactor menu.

This is only on Super Smash Bros. Brawl.

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Q: How do you unlock all characters the fastest way?
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