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You need to complete Pokemon Sapphire and Diamond and in Diamond you will need the National Dex. Go to the title screen of Diamond and press Start, then choose "Migrate from Sapphire" and follow the instructions. Choose the 6 Pokemon you want to migrate to Diamond, then confirm your choice. The 6 migrated Pokemon will be in the Pal Park and can be caught with 100% catch rate.

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Q: How do you trade from sapphire to diamond?
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