Simply right-click(or whatever the right click is configured to) in the direction you wish to toss the ender pearl to toss it. It does not work in Creative mode.
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To throw an Ender Pearl, simply put in on the bar on the bottom and, with it in your hand, right click. This will launch the pearl and teleport you where it lands. But be careful! you will take falling damage, depending on how far you throw the pearl. You cannot throw an ender pearl in creative mode.
Just hold it and right click (above ground)
You throw the eye of ender in the air and it floats to the closest stronghold. Then dig straight down and go through the stronghold to find the ender portal. Place an eye of ender in each spot, then the portal should turn on. Then just jump in.
You need to kill lots of endermen and get their ender pearls. Then, go to the Nether and kill some blazes. Make the blaze rods into blaze powder. CRaft them together to make eyes of ender. Throw them in the air and follow them until they go down and keep going down when you throw them again straqight away. Dig down but be careful - you might end up in the lava! To get to the end, fill the slots with Eyes of Ender and jump in. Beware of the Ender Dragon!
The Nether Portal - 4x8 obsidian, then set it on fire with Flint and steel The End Portal - Throw ender Eyes into the air and follow them until they go straight down. Dig down and you'll be in a strong hold. In the strong hold you have to complete the portal with more ender eyes.