you have to do everything they wish for and build their skills. get promotions and everything else and soon enough you will
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A political career in the Sims 3 can be obtained by going to the City Hall. Your sims will need a high charisma level to get to the top of the political career latter.
One of your controlled sims has to have reached the top of the natural science career. i think that career is only available with the Sims 2 University expansion.
You must reach the top of the Paranormal career (it comes with university, so if you don't have that, you're out of luck.) Then, once getting to the top, you should go into the Career Rewards section (under the backpack icon, same as aspiration Rewards and inventory) and find it.
You get a job then get the skills you need for each promotion. Sometimes you'll have to make more freinds to get a promotion but eventualy you'll reach the top of your career track and sometimes full fill a lifetime want!
It definitely helps to send your teen Sims off to college if you have University installed. While at college, your Sims will learn useful things, such as the cooking, cleaning, mechanical, body, and so forth needed for career advancement, and build up many friendships, also necessary for career advancement upon graduation. A graduate Sim will be offered a higher position in a career than one that isn't. You must continue building whichever traits the specific career calls for and gain the number friends that is necessary for the next promotion post-graduation until you can finally reach the top.