You have to defeat them.
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move tutor in second island
They are located at the Tanoby Ruins in Seven Island. first you have to move 7 boulders on the main island before the appear
a blastoise because she teaches it hydro pump which is the best move ever!!
There are move tutors everywhere there is one in particular that will teach moves that your Pokemon tried to learn but didn't that tutor can be found on two island.
he is on 2 island near the game building you need to give him tiny mushrooms or big mushrooms