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After beating the pastoria gym leader talk to the galatic grunt near the great marsh entrance. He said that you been ease droping and run away. Follow him and your rival bump into you for a battle. After the battle follow him again and keep talking to him intil he is done with running away so he will battle you. Then after beating him he will just walk toward the lake. Then you will she cynthia. Talk to her and she will talk about the psyduck having headake. She will give you a secret potion to heal their cronic headake.
You get a secret medicine from cynthia(*who later in the elite four is the champion)

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Q: How do you move the Psyduck in Pokemon Diamond?
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You have to keep following the road to the right of the psyduck until u get to the next lake. Cythia will then give it to you :)


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