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Throwing potions in minecraft are called splash potions. To make any splash potions you will need to add gunpowder to it by putting it in the brewing stand, like any other ingredient for the potion.
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To make potions last longer, you add redstone to them.
There are many potions you can make but you need many different materials to do so first you need to make awkward potions and then you add the fizz like fermented spider eyes magma cream and you can make potions of fire resistance potions of speed potions of regeneration potions of instant health which instantly heal you also instant damage and much more check the wiki by typing minecraft wiki in on google it's a very useful site that's about what you can make
Ghast tears are used to make many potions.