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You have to go to the top of Bellsprout Tower and defeat the elder, in which you will get the item Flash. This move allows you to light up any dark cave.
Up your moms @$$
When you get to violet city go to the pokemon center go left then down then you will come up on a place called route 32 and at the end you will find a pokemon center and a cave and thats union cave.
it's either a cave or the area of a shiny Pokemon
you go up to them then push them