You can join an alliance when you have built an embassy level 1, and have invitation to the alliance from the alliance leader. You can then accept the invitation from inside the embassy.
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You open your inbox and click "join alliance" Actually you have to have an embassy to join an alliance. Build one then click on it, and viola, you'll get to join an alliance. After that, read the instructions.
if you build it to 100, (it costs over 1 million of each resource) you and your alliance win the game, and the game ends.
There is no Offical biggest population for Travian
Grepolis is a game like Travian, certainly with better graphics. You may have heard of Tribal Wars. Well, Grepolis is made by the same people, but as an improvement to Tribal Wars. Help me out and join with this link: http://en.grepolis.com/invite-136310-en3 There are tons of games out there like Travian-Lord of Ultima, Ikariam, Desert Operations, etc. The OSG1 blog has a complete list of games that are similar to Travian: http://osg1.com/list-of-games/
games likekingsage tribalwars travian khanwars