Insert Pokemon Ruby and go to either route 221 or route 210 hope i helped :)
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There isn't a trainer. you need to have Pokemon ruby. then after you get the national dex you insert ruby and go to route 208 and after a few encounters zangoose will appear.
The way you can get zangoose in Pokemon heartgold is in the safari zone.
Zangoose does not appear in Pokemon sapphire, but you CAN get it. To get it, you must trade Pokemon with your friend if your friend has Pokemon ruby which is the only game you can get zangoose in. Or you can just buy Pokemon ruby.
Zangoose is only found in Pokemon Ruby, which means you have to trade it from Ruby or from someone who has one.
you catch zangoose in route 208 after getting national pokedex