Unknown are unavailable in Emerald. You must trade them from another game.
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Unown Cave doesn't exist in Pokémon Emerald. Unown only appears in the Ruins of Alph in Pokémon Gold and Silver, including their remakes, as well as in Crystal. It also appears in Tanoby Chambers in Pokémon FireRed and LeafGreen, and in the Solaceon Ruins in Pokémon Diamond, Pearl and Platinum.
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Unown (?)
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Unown