You have to go the top of the lighthouse in Olivine Town, and then you'll have to help her heal a sick Pokemon by going across the sea to a medic in Cianwood, and then bringing the medicine back to her. THEN she'll be waiting at her gym.
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moltres=mt silver zapdos=powerplant articuno=seafoam islands you have to beat the 6th gym leader in kanto to catch em
Byron
You beat the 6th gym leader.
The 6th Gym Leader In Pokemon Ruby Destiny is in Down Pour City
the 6th gym leader is in fortree city after the weather station where you get castform