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Union Cave
You find it in Union Cave.
going into the union cave for the first time a mountain climer bumps into you and gives you it :)
Check out this site it has maps of the Ice Cave http://www.pokemonelite2000.com/gsicepathmaps.html
In Pokemon Silver you can find Wooper in Route 32 but only at night and you can also find it in the Ruins of Alpha in both the grass and in the water but water-wise only via Surfing on a Pokemon and in the Union Cave you can find it in the cave as well as by surfing on the water.