On the fifth floor. Battle the rocket to the very right. He will give you the card.
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In order to get rid of Team Rocket in Saffron City, the player must go into the Silph Co. building. In Silph Co, the player must navigate all the floors of the building, defeat Team Rocket, and save the company president.
You have to beat team rocket in Silph Co
in saffron city but make sure that the team rocket grunt is sleeping
get the card key go on the 3rd floor and open 2 rooms and go on the teleporter in the 2nd room
you have to beat the team rocket boss giovani. he will be in the biggest building insaffron city. then you will be given a master ball and team rocket will leave the city. then go to the gym and beat sabrina. but be careful, she uses psychic pokemon.