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After Uxie, Azelf, and Mesprit get captured by Team Galactic, go to Veilstone City and go to the Galactic Headquarters. When you try to get to the Headquarters, a grunt will drop a key. Go to the warehouse to the west. Once you get through the building, you will fight Cyrus, the Master. He will babble about emotions and power and then he will give the Master Ball to you. Then you have to beat Saturn to get Uxie, Mesprit, and Azelf out of the jail. Alternatively, you can get multiple Master Balls by winning the lottery in the Jubilife TV Station, although the odds are very, very low.

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Q: How do you get the Master Ball on Pokemon Pearl?
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