Receive from Mr. Game at the Goldenrod Game Corner.
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It's in a building in goldenrod city.
well you can do it with cheats or by yourself
50000 coins in coin case, press [Select] 94000130 FFFB0000 62111880 00000000 B2111880 00000000 10001068 0000270F D2000000 00000000
You can find an Amulet Coin in the Goldenrod Department Store basement.
In Pokemon Yellow, you can obtain the coin case from a man sitting at a table in the cafe in Celadon City. The purpose of the case is to hold coins for use at the Game Corner. In Pokemon Yellow, the Coin Case can hold up to 9,999 coins.