It is in White Forest when Lena is the resident of the forest. If not you'll need to use the Entralink to connect with Pokemon Black and visit that version's Black City.
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Ralts is a swarming Pokemon at Route 34. You can also trade or transfer a Ralts from another game.
You will need to trade it from Pokemon White. Or you can get it at Spooky Manor in the Dream World (Over 10,000 dream points).
Ralts evolves into Kirlia at level 20.
You can't catch ralts on Pokemon leafgreen or firered because ralts is a new hoen Pokemon so it won't be available in the kanto games. Hope this helps, The Dudiest Dude On The Planet
ralts sucks until it evolves into gardevoir or galade and then its an amazing Pokemon and i personally recomend gallade.^