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Route 36 and 37
You can catch both male and female Nidoran on Route 35 and Route 36.
Talk to the man just west of Violet City on Route 36.
You cannot get it in Pokemon Silver, but you can in SoulSilver or HeartGold. You have to go to Route 36.
Catch a Vulpix on Route 7, 8, 36, 37 or 48, then evolve it using a Fire Stone.