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You actually begin the game with the national dex.
You have to migrate six Pokemon from ruby, sapphire, or emerald in order to get into pal park. (after the national dex) Get the national dex. (before the national dex)
Go to Cerulean Cave. To get there, you must get the ruby and the sapphire and get the national dex.
The last Pokemon on the national dex is Arceus.
There are 210 in the Sinnoh Dex, 493 in the National Dex {including EVENT Pokemon}