You will find Aipoms in trees in Route 29 to 33 and Route 42 to 46. They are uncommon and they appear anytime. So it won't take very long to find one.
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headbutt tree
No, he doesn't start evolving until the next generation of pokemon.
You can obtain an Aipom by headbutting trees.
aipom's evole is a Pokemon from the next generation after emerald so its impossible to receive him.
aipom does not evolve inpokemon emerald