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Get a jynx from Pokemon FireRed or leafgreen then put it in the daycare with a ditto and wait when you come back you can get an egg and when it hatches its smoochum.

You can't catch smoochum you need to breed a jynx with a ditto to get it.

Breed two jinx (leave in daycare)

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Q: How do you get a smoochum in emerald?
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