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To get a Potion of Harming in minecraft:

Brew Awkward Potions: Use Nether Wart on Water Bottles in a Brewing Stand.

Brew Potion of Poison: Add a Spider Eye to the Awkward Potions.

Brew Potion of Harming: Add a Fermented Spider Eye to the Potions of Poison.

For an improved version, add Glowstone Dust to make Potion of Harming II or Gunpowder to make it a Splash Potion of Harming.

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