there isnt any dusk balls in fire red, they were introduced in generation iv
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no you can only get a dusk stone on Pokemon diamond and pearlYou can't.
first of all you dont get a dusk stone in firered secondly you must mean the moon stone
Go to Pastoria City and there will be two people at the counter. Press A in front of the guy on the left and he sells dusk balls, quick balls, and i think net balls.
In a shop
you can get dusk balls at the elite four hospital along with a bunch more different ones that are really useful.