Only Jirachi has Doom Desire.
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level 70
The move is Doom Desire
On the turn Doom Desire is selected, it will do nothing other than state that the user has chosen Doom Desire as its destiny. Two turns later, Doom Desire will do damage against the target, using the Special Attack stat of the user and Special Defense stat of the target at the time of use.
Sypher is under the rock of doom. You know it.
All Pokemon with a water-type can learn it. There are some other Pokemon that can learn it, but mostly water-Pokemon.