you have to beat Tabuu, get all the character's trophies, and get through it all.
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you find 20 zeon coins
What you need to do is beat Tabbu and then after that get Wolf, Toon link and Jiggly puff. To get 100% you need to get as many trophies as you can. Get trophies from those blue and yellow boxes or turn your enemies into trophies.
You can unlock Falco one of three ways. 1. Play 50 Brawl Matches 2. Have him join in SubSpace Emissary 3. Complete 100-man brawl
in everyone in brawl 100 times
nothing u just get a specail tropghy