I did this myself. First, you must either find a suitable building spot or you must leave whatever town you are in. then you have to pay ($200)? to found the town. It will be founded with what name you give it in 8 hours.
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Go either east or west.
Alamos Town does not appear in the Pokemon Diamond version of this game. It is in the movie, but not on this game.
Slowpoke Well can be found at the east entrance of Azalea Town. To get there, travel south from Violet City. When you reach Union Cave, travel through. As soon as you exit, head west. This will take you to Slowpoke Well and Azalea Town.
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how to play this game