The station is the upper-left-most part of Saffron City. In order to earn the ability to use the Magnet Train, complete the Power Plant part of the game, talk to Copycat in the house just south of the station, talk to the president of the Pokémon Fan Club in Vermillion City and receive the Lost Property (if you haven't already), take the Lost Property back to Copycat, and she'll give you the Pass. You can now ride the Magnet Train and go between Goldenrod City (Johto) and Saffron City (Kanto) whenever you want!
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The Copycat is in Saffron City, near the train station.
Copycat lives in the house almost directly across the train station in Saffron City.In Saffron City.
No, there is no map of Saffron City. But there is a map of Hoen which has Saffron City on it.
In Silph Co in Saffron city.
Beside the gym in saffron city