On Pokemon Sapphire, you can find a skitty on route 116, near the Rusturf Tunnel, but it's very hard to find. You have about a 2% chance of finding one!
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Skitty as well as other hoenn Pokemon cannot be found in firered all hoenn Pokemon must be traded to you from ruby, sapphire, emerald, Pokemon colosseum and Pokemon xd gale of darkness.
You cannot find skitty in-game. Tansfer it from another generation
Skitty evolves into Delcatty through the use of a Moon Stone in Pokemon Ruby and Sapphire.
The only way I know is to look behind the Pokemon Mansion or to migrate one from Ruby, Sapphire, or Emerald.
Skitty can be found on route 116 However, it is very hard to find but trust me its there!