yes in the cave place but you have to have a cidiquil, qualava, or a typhlosion with you
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(you don't find it you breed 2 magmar and when egg hatches you've got magby)You don't necessarily have to breed two magmar's you could just get a ditto and breed a magmar with the ditto, as with anyother Pokemon except legendary Pokemon.By the pokewalker.
on the pokewalker
If You want to catch magby in Pokemon pearl you have to: Insert a Pokemon leafgreen game in the GBA slot. Goto stark Mountain and search there eventualy you will find a magby if u don't start using pokeradar then u will find it Good Luck<(-_-)>
You can't you can only find snorunt in the pokewalker
first you need leaf green version, insert it into your ds, then go to stark mountain keep looking until you find magby once you find and catch magby train him to level 30 then you will have magmar.