it depends what kind of Pokemon because if they are level evolvers no but if they are stone evolvers yes
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no when it is level 100 you cant evolve it any more
100
Vulpix evolves at level 100. does not. can only evolve with fire stone.
It depends on the Pokemon. Some of them you have to evolve by using stones. Others don't evolve at all. There is not one level that all Pokemon evolve at(unless you use an everstone on them until level 99, then level it up once more to level 100, but that would be a waste of time).
Yes. Level 100 Pokemon cannot earn Exp. Points any longer, but otherwise are completely normal.