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Answer
Bring Both Married Sims Relationship Down To Best Friends Or Friends Status Through Negative Social Cues. Then Have One Of Them Attempt To "Kick Out" The Other Sim. That Other Sim Will State: "Fine, We Are Not Married Anymore. But I Still Live Here." Both Your Sims Will Be Officially Divorced & Free To Marry Another Sim.
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You can get your sim pregnant in Sims 2 Apartment Life and Sims 2 Double Deluxe.
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