After you use Samus's final smash her suit will break and you will play as Zero Suit Sumus.
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Samus can only change back and forth between Samus and Zero Suit Samus by using her final smash.
Select Samus. After you select her, hold in "c" until the brawl starts. You're 0-suit Samus!
No, you cannot do this.
Nope, Brawl only.
Well the easiy way is to use your super move and you turn to zero suit samus